What’s the simplest way of balancing out the light on a headshot using Photoshop?

What's the simplest way of balancing out the light on a headshot using Photoshop? I've taken a nice business headshot for somebody, but annoyingly the key light wasn't quite central on him, so one side of his face is slightly brighter. I'd love to know people's advice on the simplest way to balance the light across his face using Photoshop. None of it is overexposed, thankfully, so lots of information to play with. Thanks
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